Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_eb2648e65ad8850515bd727a122f1186 |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01L21-02219 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-025 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01L21-02208 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-21 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-70 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01L21-0228 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-462 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-26 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01L21-02617 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C23C16-45525 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C23C16-442 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C23C16-505 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C23C16-50 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1616 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01L21-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-10 |
filingDate |
2016-08-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate |
2018-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2d6540ee44f2c44e3096614aa51a99b8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_129e904278b9eb2274719baa54fb0ab5 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_08430a30ddf429118627de058d4d64f1 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a3a4ede468ccfa0faafb7044f90c8319 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_050017a2a160c7fc9d3eef9e5156d931 |
publicationDate |
2018-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
US-9920078-B2 |
titleOfInvention |
Halogen free synthesis of aminosilanes by catalytic dehydrogenative coupling |
abstract |
Compounds and method of preparation of Si—X and Ge—X compounds (X═N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X═N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si-containing films. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10875877-B2 |
priorityDate |
2013-09-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |