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filingDate 2003-10-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2005-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ffc8f7e88bca5d83b63b81b3595aa06a
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publicationDate 2005-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-6919468-B2
titleOfInvention Asymmetric group 8 (VIII) metallocene compounds
abstract Asymmetric, disubstituted metallocene compounds have the general formula CpMCp′ where M is a metal selected from the group consisting of Ru, Os and Fe; Cp is a first substituted cyclopentadienyl or indenyl moiety that includes at least one substituent group D 1 ; Cp′ is a second substituted cyclopentadienyl or indenyl moiety that includes at least one substituent group D 1 ′. D 1 is different from D 1 ′. D 1 is X; C a1 H b1 X c1 ; C a2 H b2 X c2 (C═O)C a1 H b1 X c1 ; or C a2 H b2 X c2 OC a1 H b1 X c1 , where X is a halogen atom or nitro group; a1 is an integer between 2 and 8; b1 is an integer between 0 and 2(a1)+1−c1; c1 is an integer between 0 and 2(a1)+1−b1; b1+c1 is at least 1; a2 is an integer between 0 and 8; b2 is an integer between 0 and 2(a2)+1−c2; and c2 is an integer between 0 and 2(a2)+1−b2; and D1′ is X; C a1 H b1 X c1 ; C a2 H b2 X c2 (C═O)C a1 H b1 X c1 ; or C a2 H b2 X c2 OC a1 H b1 X c1 , where X is a halogen atom or nitro group; a1 is an integer between 1 and 8; b1 is an integer between 0 and 2(a2)+1−cl; c1 is an integer between 0 and 2(a1)+1−b1; b1+c1 is at least 1; a2 is an integer between 0 and 8; b2 is an integer between 0 and 2(a2)+1−c2; and c2 is an integer between 0 and 2(a2)+1−b2. The compounds can be employed as precursors in film deposition processes.
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