http://rdf.ncbi.nlm.nih.gov/pubchem/patent/DE-102013211231-B4

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filingDate 2013-06-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2016-05-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2016-05-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber DE-102013211231-B4
titleOfInvention Method for forming a tandem photovoltaic unit
abstract A method of forming a tandem photovoltaic device, the method comprising: Providing (102) solid germanium or a germanium layer formed on a silicon substrate; Wet etching the germanium layer using an acidic etchant containing phosphoric acid, hydrogen peroxide and ethanol in a ratio of 1: 1: 1; Forming pyramidal shapes (106; 108) in the germanium layer such that (111) crystal faces (104) are exposed to form a textured surface; Doping an upper surface (110) of the germanium layer to form a first pn junction on or above the textured surface; Depositing a first semiconductor layer (112) following the textured surface on the upper surface, the first semiconductor layer containing a GaAs layer or alloys thereof; Doping a portion of the first semiconductor layer to form a second pn junction (132); Depositing a second semiconductor layer (116) following the profile of the textured surface on the first semiconductor layer, the second semiconductor layer containing a GaP layer or alloys thereof; and Doping a portion of the second semiconductor layer to form a third pn junction (134).
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