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publicationDate 2022-12-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2022249276-A1
titleOfInvention Gas-phase reduction device for carbon dioxide and gas-phase reduction method for carbon dioxide
abstract Provided is a gas-phase reduction device 100 which is for carbon dioxide and which performs a catalytic function by irradiation with light to cause an oxidation-reduction reaction. The gas-phase reduction device 100 comprises: an oxidation tank 1 into which an aqueous solution 3 is introduced; a reduction tank 4 to which carbon dioxide is supplied; a semiconductor photoelectrode 2 which is disposed in the aqueous solution 3; and a porous electrode-supported electrolyte membrane 20 which is a joined body of an electrolyte membrane 6 and a porous reduction electrode 5 and which is disposed between the oxidation tank 1 and the reduction tank 4 so that the electrolyte membrane 6 faces the oxidation tank 1 and the porous reduction electrode 5 faces the reduction tank 4. The voltage between a reference electrode 15 which is disposed in the aqueous solution 3 and a reference electrode 16 which is disposed in contact with the electrolyte membrane 6 is measured by a voltmeter 14, and a control unit 11 increases the voltage between the semiconductor photoelectrode 2 and the porous reduction electrode 5 depending on a change in the voltage between the reference electrodes 15 and 16 from an initial value at a start of a reaction. The control unit 11 includes a solar cell 12 and a constant-voltage power supply 13. The solar cell 12 is disposed on an extension line of a straight line from the light source 9 toward the semiconductor photoelectrode 2, and uses light that has been emitted to and has passed through the semiconductor photoelectrode 2 to generate electricity.
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