http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2007096342-A1

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filingDate 2007-02-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9ad58a3c59225a0d9fa85e5999faea33
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publicationDate 2007-08-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2007096342-A1
titleOfInvention Process for the preparation of an alkanediol and a dialkyl carbonate
abstract An alkanediol and a dialkyl carbonate are prepared in a process comprising: (a) contacting an alkylene carbonate with an alkanol feedstock under transesterification conditions in a reactive distillation zone to obtain a top stream comprising dialkyl carbonate and the alkanol and a bottom stream comprising the alkanediol; (b) separating the top stream comprising dialkyl carbonate and the alkanol into an alkanol-rich stream and a dialkyl carbonate-rich stream; (c) recovering the dialkyl carbonate, optionally after further purification, from the dialkyl carbonate-rich stream; and (d) recycling at least part of the alkanol-rich stream to the reactive distillation zone as part of the alkanol feedstock, wherein the alkanol-rich stream is split in at least two portions, and at least one portion is condensed and freed from compounds with a lower boiling point than the alkanol. The process is especially suitable for the production of propylene glycol and dimethyl carbonate from propylene carbonate and methanol.
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priorityDate 2006-02-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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