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filingDate 2005-07-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2006-01-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2006009229-A1
titleOfInvention Solid phosphoric acid catalyst and methods of dimerizing olefin with the same
abstract A solid phosphoric acid catalyst which attains high activity and dimer selectivity in olefin dimerization reactions; and efficient methods for olefin dimerization which comprise using the catalyst. The solid phosphoric acid catalyst comprises a siliceous support and one or more phosphoric acids deposited thereon, the proportion of orthophosphoric acid in the phosphoric acids deposited being 60 mol% or higher in terms of phosphorus atom amount. The solid phosphoric acid catalyst is prepared by contacting a siliceous support with an aqueous phosphoric acid solution and then drying the support, the preparation steps being conducted at a temperature lower than 100°C. Also provided is a method in which an olefin-containing raw material is brought into contact with the catalyst. Furthermore provided are: the method in which the olefin-containing raw material is regulated so as to contain water in an amount of 10-1,000 mass ppm; the method in which the olefin-containing raw material is brought into contact with the solid phosphoric acid catalyst in a liquid phase; and the method in which the olefin is a C3-7 monoolefin.
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