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filingDate 2015-07-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2018-04-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-9947576-B2
titleOfInvention UV-assisted material injection into porous films
abstract Methods are described for reducing shrinkage experienced by porous films on a patterned substrate. The film may be a silicon-and-hydrogen-containing layer which further contains one or two of carbon, oxygen and nitrogen. Shortly after deposition, the silicon-and-hydrogen-containing layer is treated by concurrent exposure to a relatively small molecule precursor (e.g. NH 3 or C 2 H 2 ) and a source of UV light. The treatment may reduce subsequent shrinkage experienced by the porous film even at the bottom of the film due to the significant penetration prior to reaction. The treatment may reduce shrinkage at the bottom of a trench filled with the porous film.
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