Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_23a4e0c875bf1ac2b8a3b76517de6c7d |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2602-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2603-74 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-07 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B41-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-48 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B41-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B41-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-30 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07J21-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07J43-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07J33-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07J71-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-48 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B41-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B41-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B41-02 |
filingDate |
2003-08-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate |
2007-03-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7ed8d8beb05e2cdb1a15c642028eada5 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_433c9076992b24bc6fcf03e79bc75fe3 |
publicationDate |
2007-03-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
US-7196191-B2 |
titleOfInvention |
Catalytic oxidation of C—H bonds |
abstract |
The invention provides a catalytic, chemospecific and stereospecific method of oxidizing a wide variety of substrates without unwanted side reactions. Essentially, the method of the instant invention, under relatively mild reaction conditions, catalytically, stereospecifically and chemospecifically inserts oxygen into a hydrocarbon C—H bond. Oxidation (oxygen insertion) at a tertiary C—H bond to form an alcohol (and in some cases a hemiacetal) at the tertiary carbon is favored. The stereochemistry of an oxidized tertiary carbon is preserved. Ketones are formed by oxidizing a secondary C—H bond and ring-cleaved diones are formed by oxidizing cis tertiary CH bonds. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2013113294-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10093695-B2 |
priorityDate |
2002-08-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |