abstract |
A polysiloxane comprising a linear polydiorganosiloxane chain joined at one terminus to an acrylic-functional end group, and joined at its other end to a cross-linked MTQ moiety comprising a multiplicity of monofunctional siloxane units (M), trifunctional siloxane units (T), and tetrafunctional siloxane units (Q), wherein the concentration ratio of M units to the sum of T units and Q units, M/(T+Q), in the MTQ moiety is from about 0.55 to about 0.75, and wherein the number of siloxy repeating units in the linear polydiorganosiloxane chain is from 25 to 1,000. The M and or /T units may also contain (meth)acrylate groups. The MTQ/silicone hybrid resins of the invention are curable by UV radiation, to provide high tensile strength silicone compositions having utility in potting and conformal coating apllications. |