abstract |
PCT No. PCT/EP89/01449 Sec. 371 Date Aug. 2, 1990 Sec. 102(e) Date Aug. 2, 1990 PCT Filed Nov. 30, 1989 PCT Pub. No. WO90/07504 PCT Pub. Date Jul. 12, 1990.Composition for the oxidative dyeing of hair based on a combination of developer substances and coupler substances contains, as developer substance, a diaminopyrazol of the general formula (I), <IMAGE> (I) wherein R1, R2 and R4 are identical or different and designate hydrogen, alkyl with 1 to 4 carbon atoms, hydroxyalkyl with 2 to 4 carbon atoms, benzyl or phenyl, and R3 is hydrogen, alkyl with 1 to 4 carbon atoms, hydroxyalkyl with 2 to 4 carbon atoms, with the proviso that the amino groups are in 3,4 or 4,5 position, or its physiologically tolerated, water-soluble salt, new diaminopyrazol derivatives of the above general formula I are also described herein in which R1 is methyl or benzyl and the R2 and R4 are either benzyl, phenyl, hydrogen, alkyl with 1 to 4 carbon atoms or hydroxyalkyl with 2 to 4 carbon atoms and R3 is either hydrogen, alkyl with 1 to 4 carbon atoms or hydroxylakyl with 2 to 4 carbon atoms. The compounds of formula I are developer substances which are very favorably tolerated physiologically and enable brilliant hair coloring of great depth of color in the red range. |