http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4987270-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0efa077d881a96aeb1e29b21ef1bbb58 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-34 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C33-20 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-34 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-44 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-34 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-04 |
filingDate | 1989-08-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 1991-01-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_210210e10a19724684ec42336bdac2b3 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a39e1676199d48090e7ec6cc0e946140 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ae67a0d3e06aa489b7c9e8e8944504a8 |
publicationDate | 1991-01-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-4987270-A |
titleOfInvention | Preparation of 3-arylisobutyl alcohols |
abstract | 3-Arylisobutanols of the general formula I <IMAGE> (I) where R1 and R2 are each hydrogen or an alkyl or cyclo-alkyl radical of not more than 8 carbon atoms, preferably alkyl of 1 to 4 carbon atoms, are prepared by a process in which an arylcarbinol of the general formula II <IMAGE> (II) is reacted with n-propanol in the presence of a catalytic amount of an alkali metal hydroxide or an alkali metal alcoholate at from 250 DEG to 350 DEG C. in a closed reaction vessel. The process is of particular importance for the preparation of 3-arylisobutanols of the formula I, where R1 is alkyl of 1 to 4 carbon atoms and R2 is hydrogen. The p-methyl-, p-isopropyl- and p-tert-butylphenylisobutanols obtained here in very good selectivity are useful intermediates for the desirable scents jasmorange, cyclamen aldehyde and Lysmeral TM (Lilial TM ). |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2021102541-A1 |
priorityDate | 1988-09-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 74.