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filingDate 1982-01-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1985-05-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4519986-A
titleOfInvention Process for preparation of ultrapure thorium fluoride
abstract The specification discloses a process for the preparation of ultrapure thorium fluoride (ThF 4 ) having minimized water content and consequent maximized optical transmission of 10.6 micrometer radiation. First, thorium oxide is reacted with aqueous hydrofluoric acid to form a solid reaction product, which is then dried under controlled heating to form a hydrated thorium fluoride with a predetermined amount of hydration, namely ThF 4 .xH 2 O where x is equal to 0.39. The hydrated thorium fluoride is exposed to a reactive atmosphere of hydrofluoric acid vapor and a selected fluoride compound in the gas phase at elevated temperature for a predetermined period of time. The reactive atmosphere removes substantially all of the water and water-derived impurities from the hydrated thorium fluoride to produce ultrapure thorium fluoride which is highly transmissive to 10.6 micrometer radiation.
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