abstract |
This disclosure is directed to preparing deashed, precious metal catalyst-containing, partially fluorinated active carbon particles of the formula CFx, where x ranges from 0.1 to about 0.18, preferably using either platinum or silver as the catalyzing material, which can be incorporated into an active layer component of a gas electrode, e.g., an oxygen (air) cathode suitable for use in a chlor-alkali electrolytic cell for producing chlorine and caustic while conserving electrical energy. These particles are deashed to have a B.E.T. surface area of at least 600 m2/g and contain less than about 4 weight percent ash. Active electrode layers containing such particles demonstrate an unusually desirable combination of resistance to corrosion, retention of conductive properties and retention of catalytic surface area. |