abstract |
The present invention discloses a nitrogen-containing luminescent particle, characterized in that a structure of the nitrogen-containing luminescent particle is divided into an oxygen poor zone, a transition zone, and an oxygen rich zone from a core to an outer surface of the particle depending on an increasing oxygen content, the oxygen poor zone being predominantly a nitride luminescent crystal or oxygen-containing solid solution thereof, the transition zone being predominantly a nitroxide material, the oxygen rich zone being predominantly an oxide material or oxynitride material; the nitride luminescent crystal or oxygen-containing solid solution thereof has a chemical formula of M m-m1 A a1 B b1 O o1 N n1 :R m1 , the nitroxide material has a chemical formula of M m-m2 A a2 B b2 O o2 N n2 :R m2 , the oxide material or oxynitride material has a chemical formula of M m-m3 A a3 B b3 O o3 N n3 :R m3 . The nitrogen-containing luminescent particle and the nitrogen-containing illuminant of the present invention have good chemical stability, good aging and light decay resistance, and high luminescent efficiency, and are useful for various luminescent devices. The manufacturing method of the present invention is easy and reliable, and useful for industrial mass production. |