http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2284330-C1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_10efc646a4dd605c2f09c493718f5b81 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-09 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-40 |
filingDate | 2005-07-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2006-09-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bd60b65be2104baf372048c7ecabcc9c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5821cc71f74aa93090ef96eb449f568b http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0a2a11ede2171be6b1dc94e751b6813c |
publicationDate | 2006-09-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | RU-2284330-C1 |
titleOfInvention | Method for preparing phosphorus-chlorine-containing methacrylates |
abstract | FIELD: chemistry of organophosphorus compounds. n SUBSTANCE: invention relates to the improved method for synthesis phosphorus-chlorine-containing methacrylates that can be used in synthesis of polymeric, among them, uncolored, optically transparent and composition materials with reduced inflammability. Invention describes a method for synthesis of phosphorus-chlorine-containing methacrylates of the general formula: n wherein R means lower alkyl, chloroalkyl, alkoxyl, phenoxyl or group of the formula: n R 1 means lower alkoxyl, phenoxyl or group of the formula: n Method involves interaction of phosphoric pentavalent acid chloroanhydrides with methacrylic acid glycidyl ester at heating in the presence of hexamethylenephosphorotriamide or dimethylformamide as a catalyst wherein catalyst is taken in the amount 0.3-0.6% of reagents mass, and process is carried out at rise of temperature from 40°C to 80°C in the presence of compound chosen from the group: alkyl- or alkoxy-substituted phenols taken in the amount 0.03-0.3% of reagents mass. Method provides decreasing water absorption of (co)polymerization products of synthesized phosphorus-chlorine-containing methacrylates and reducing retention time of surface stickiness of fiber glass synthesized on their basis and at retention the level of other properties, among them transparence and colorless. n EFFECT: improved method of synthesis, improved and valuable properties of compounds. n 2 tbl, 10 ex |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2655973-C2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2551660-C1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2601748-C1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2549877-C1 |
priorityDate | 2005-07-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 72.