http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-20060129947-A

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filingDate 2006-06-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2006-12-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber KR-20060129947-A
titleOfInvention Functional Molecular Device and Manufacturing Method Thereof, and Functional Molecular Device
abstract Provided is a functional molecular element having a novel structure capable of reducing contact resistance at an interface between a constituent molecule and an electrode, a manufacturing method thereof, and a functional molecular device.n n n First of all, a linear tetrapyrrole, which has a substantially disk-like structure of porphyrin-like appearance, and a flexible composed of an alkyl chain. Closely adhered to the surfaces of the electrodes 5 and 6 using a π electron conjugated molecule 1 having flexible side chains 3. The molecular layer is formed into a single layer. Next, the π-electron conjugated molecule (1) or other π-electron conjugated molecule is laminated by π-π stacking on the π-electron conjugated molecule (1). pilling to form an array structure 4. In the π-electron conjugated molecule 1 forming the molecular layer of the first layer of the array structure 4, the flexible side chain 3 is adsorbed onto the surface of the electrode 5 (or (6)). As a result, it is fixed so that the disk surface of the skeleton part 2 may closely contact with the surface of the electrode 5 (or (6)). In addition, the stacking direction of the molecular layer after the second layer of the array structure 4 is controlled by π-π interaction.
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