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filingDate 1982-09-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_70e2ffe7dfc92d38cbabca0f7968f069
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publicationDate 1984-03-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-S5944393-A
titleOfInvention Thiophosphatidyl ethanolamine derivative, preparation thereof and agricultural and horticultural germicide
abstract NEW MATERIAL:A thiophosphatidyl ethanolamine derivative of formula I (R and R 1 are alkyl or fatty acid residue). n EXAMPLE: 2-Oleoyl-3-palmitoyl-1-sn-thiophosphatidyl ethanolamine. n USE: An agricultural and horticultural germicide usable safely without giving phytotoxicity to crops. n PROCESS: A glycerol derivative of formula II is reacted with a dichloro(N-2,2,2- trichloroethoxycarbonyl-2-aminoethyl)thiophosphate of formula III in a solvent, e.g. tetrahydrofuran (THF), in the presence of a condensing agent, e.g. sodium hydride, to prepare an N-(2,2,2-trichloroethoxycarbonyl)thiophosphatidyl ethanolamine derivative of formula IV, which is then reacted with zinc in acetic acid to remove the protecting group of the amino group. Thus, the aimed compound of formula I is prepared. n COPYRIGHT: (C)1984,JPO&Japio
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