abstract |
(57) [Summary]nA general formula (1) (wherein, X is a hydrogen atom or hydrocarbon water) Elementary group or acyl group, Y is hydrogen atom, hydrocarbon group, halogen Hydrocarbon group, -COR 1 , -OR Two , -COOR Three , -CN, -CONH Two , -NO Two , -NR Four R Five ,halogen Atom, SO Four R 6 Or SO Three R 7 , M is an integer from 1 to 7, and n is It is an integer of 3 or more. ) Cyclic phenol sulfide represented by Offer things.n SOLUTION: In the general formula (2), Y is a hydrogen atom or It is a hydrocarbon group. ) Phenols represented by 0.1 gram equivalent or more per 1 gram equivalent of enols Elementary sulfur is 0.0 per 1 gram equivalent of the phenols. Alkali metal reagent and alkaline earth of more than 05 gram equivalent Presence of at least one metal reagent selected from the group of metal reagents Make them react in the presence. If necessary, the obtained cyclic pheno Derives the hydroxyl group of sulfur sulfide and the substituent of Y to other substituents You. |