http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2014114257-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_046e16bd6918ef3cd62184605b15a413 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-149 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-60 |
| classificationIPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-46 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-149 |
| filingDate | 2012-12-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_fe10ff3ff49777b89f66431ef323b78e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_152388868f74f13c1f0d7a8eda840909 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_db51e739cdf637586bbd879f8287e334 |
| publicationDate | 2014-06-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | JP-2014114257-A |
| titleOfInvention | Method for reducing halogen-substituted benzoates using ruthenium carbonyl complexes |
| abstract | Disclosed is a method for reducing a benzoic acid ester, in which dehalogenation is suppressed, using an easily available catalyst. In the presence of a ruthenium complex represented by the following formula (1), an benzoic acid ester having an aromatic ring substituted with a halogen atom is used to reduce the ester group with hydrogen gas using an aromatic hydrocarbon as a solvent, A method for reducing a benzoic acid ester in which dehalogenation is suppressed, which produces benzyl alcohol in which an aromatic ring is substituted with a halogen atom. RuXY (CO) (L) (1) (wherein X and Y represent an anionic ligand, and L represents a tridentate aminodiphosphine ligand represented by the following formula (2)). (Wherein R 1 , R 2 , R 3 , and R 4 may be the same or different, and each represents an alkyl group, a cycloalkyl group, an aryl group, etc., and Q 1 and Q 2 are the same) Or a divalent alkylene group which may have a substituent, a divalent cycloalkylene group which may have a substituent, and the like. [Selection figure] None |
| isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10407448-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2017131226-A1 |
| priorityDate | 2012-12-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 98.