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filingDate 2009-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2011-08-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2011523619-A
titleOfInvention Method for producing crystalline metallosilicate
abstract The present invention comprises a crystallite having an inner portion and an outer portion, wherein the ratio of Si / metal is higher in the outer portion than in the inner portion, and metal and silicon are continuously distributed in the crystal cross section of the crystallite. A method for producing a crystalline metallosilicate composition. (A) An aqueous medium containing an OH - anion and a metal source is prepared, (b) an aqueous medium comprising an inorganic silicon source and an optional template agent is prepared, and (c) optional Prepare an optional water-insoluble medium containing an organic silicon source, and (d) mix the water-soluble media (a) and (b) with the optional component (c) under effective conditions (e ) The reaction mixture (a) + (b) + (c) is cooled to room temperature, (f) the pH of the reaction mixture is lowered by at least 0.1, and (g) the mixture obtained in step (f) is added to the desired metallosilicate. Favorable conditions for continued crystallization, (h) recovering the desired metallosilicate. The Si organic / Si inorganic ratio in the mixture (a) + (b) + (c) before crystallization is <0.3 and the molar ratio of OH − / SiO 2 is at least 0.3.
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