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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/D01F6-18
filingDate 2008-04-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_36f4976dddcb6c2d7e18912bba84e094
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7ac5b2e13758b0cde73e0b7459e1153b
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6043758a0dd3631fd60577e4e9f80e39
publicationDate 2009-10-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-2009249798-A
titleOfInvention Method for producing carbon fiber precursor fiber
abstract 【Task】 In order to reduce the cost of carbon fibers, a PAN-based polymer for producing carbon fiber precursor fibers that can increase the spinning speed by having a specific molecular weight distribution is used, and the amount of residual acrylonitrile is small and gel is produced. The present invention proposes a method for stably producing carbon fiber precursor fibers with less foreign matter and with reduced contamination. [Solution] A polyacrylonitrile system in which Mz / Mw, which is a ratio of the weight average molecular weight Mw and the Z average molecular weight Mz, obtained by copolymerizing at least one acid monomer selected from the group consisting of acrylic acid, methacrylic acid and itaconic acid is 2 or more Spinning in which the polymer is dissolved in a solvent, the content ratio of acrylonitrile is 0.001 to 0.1% by weight, and satisfies at least one requirement selected from the following [a] to [c] A method for producing a carbon fiber precursor fiber obtained by spinning a solution to obtain a coagulated yarn, followed by washing with water to obtain a carbon fiber precursor fiber. [A] In the polyacrylonitrile-based polymer, the hydrogen ion of the carboxylic acid group derived from the acid monomer is 0 to 0.00% of the contained carboxyl group by at least one ion selected from the group consisting of ammonium ion and sodium ion. 3 equivalents are replaced. [B] The spinning solution contains 0.01 to 3% by weight of an alkylating agent based on the weight of the spinning solution. [C] The spinning solution contains 0.01 to 3% by weight of an organic carboxylic acid having a boiling point of 200 ° C. or more based on the weight of the spinning solution. [Selection figure] None
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