http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2007238525-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_9019c0ce5cb7b82c85e121f6cac86dce |
classificationIPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B53-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B61-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C271-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C269-06 |
filingDate | 2006-03-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b28c3136983ad56ff45f359a2c969207 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d7fab94a1d8e9b528ca8f1a9e3bce182 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ca2d87a5bcbc561185572275a899ae14 |
publicationDate | 2007-09-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-2007238525-A |
titleOfInvention | Process for producing optically active β-hydroxyimine compound |
abstract | The present invention provides a technique for performing an addition reaction of an encarbamate and an aldehyde with high diastereoselectivity and high enantioselectivity. A method for producing an optically active β-hydroxyimine compound, wherein an addition reaction of an encarbamate and an aldehyde is carried out in the presence of a compound represented by the following formula (I) and a rhodium complex. (In the formula, Ar represents an optionally substituted aryl group, R 6 and R 7 each independently represents a hydrogen atom or an optionally substituted alkyl group or aryl group, R 6 and R 7 may form the same ring together). The present invention can produce an optically active β-hydroxyimine with high diastereoselectivity and good enantioselectivity. Further, the asymmetric reaction can be carried out under relatively mild conditions, such as being able to be carried out at a reaction temperature of around 0 ° C. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-109503660-B http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-109503660-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2008222621-A |
priorityDate | 2006-03-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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