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filingDate 2020-07-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_44e4d04c8d77e68d2a7d1a8a83d3d508
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publicationDate 2022-01-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-3937281-A1
titleOfInvention Method for operating an sofc for the combined production of electricity and nitric oxide
abstract The present disclosure discloses a method for the combined production of electricity and nitric oxide. The method comprises the steps of: providing an SOFC comprising an anodic side comprising a solid gas-permeable anode, a gas inlet and a gas outlet, a cathodic side comprising a solid gas-permeable cathode and a gas inlet and a gas outlet, and a fully dense solid electrolyte, separating the cathodic side from the anodic side; introducing an oxygen-containing gas in the inlet of the cathodic side of the SOFC; introducing an ammonia-containing gas stream in the inlet of the anodic side of the SOFC; collecting nitric oxide at the outlet of the anodic side and collecting a current flowing between the anodic side and the cathodic side. The cathode comprises a material suitable for reducing the oxygen in the oxygen-containing gas and the anode comprises a composition A<sub>1-X</sub>A'<sub>X</sub>B<sub>1-Y</sub>B'<sub>Y</sub>O<sub>3-δ</sub>, wherein A is selected from the group consisting of La, Y, Sm, Pr, Nd and Gd, A' is selected from the group consisting of Ca, Sr and Ba, B and B' are each independently selected from the group consisting of Co, Fe, Mn, Cr and V or mixtures thereof, X ranges from 0.05 to 0.6 and in particular from 0.1 to 0.4, Y ranges from 0 to 1 and δ ranges from 0.025 to 0.3 The present disclosure further relates to an SOFC and stack thereof for performing the method of the disclosure, to a method for producing nitric acid and to a system thereof, and to the use of the anode in the methods and SOFC and stack thereof.
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