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publicationDate 2016-08-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-3049499-A1
titleOfInvention Amine substituted trisilylamine and tridisilylamine compounds
abstract Halogen free amine substituted trisilylamine and tridisilylamine compounds and a method of their preparation via dehydrogenative coupling between the corresponding unsubstituted tnsilylames and amines catalyzed by transition metal catalysts is described. This new approach is based on the catalytic dehydrocoupling of a Si-H and a N-H moety to form an Si-N containing compound and hydrogen gas. The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The -Si-N containing products are halide free. Such compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si containing films.
priorityDate 2013-09-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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