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filingDate 1987-10-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_06ed6abb469aa65a2f11324307579deb
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publicationDate 1993-05-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0542320-A1
titleOfInvention Process for the preparation of an aromatic polyester
abstract In a continuous process for the production of aromatic polyesters by polycondensation of 9,9-bis (4-hydroxyphenyl) fluorene with iso-phthaloyl chloride and / or tere-phthaloyl chloride as dicarboxylic acid halide according to the two-phase interface polycondensation process, the aqueous phase consists first of all from a solution of the diphenols, alkali metal hydroxide to form the diphenolates and optionally a phase transfer catalyst in water or in a mixture of water and an organic solubilizer with an organic solvent; a fine pre-emulsion is continuously produced which, together with the organic liquid phase forming the acid chloride solution, is supplied to a dispersing device in quantities such that the compounds participating in the polycondensation reaction are mixed in the dispersing device in constant proportion to one another to form a reaction emulsion, which then one or passes through several dispersing devices and / or static mixers, during which the polycondensation takes place and is ended. The phases are then separated and the polyester formed is precipitated from the organic phase by introducing acetone.
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