| abstract |
A manufacturing method of polyolefin is disclosed wherein the catalyst used for the polymerization of α-olefins at a temperature lower than the melting point of polymer in the precence of said Ziegler type catalyst and hydrogen comprises ofn (A) solid catalyst ingredient (A) obtained by allowing the reaction product ofn (i) at least one of metallic mangnesium and hydroxylated organic compounds and oxygen-containing organic compounds of magnesium, (ii) at least one oxygen-containing organic compound of titanium, (iii) at least one organoaluminum compound, and/or (iv) at least one silicon compound nto react withn (v) at least one halogenated aluminum compound, (B) at least one catalyst ingredient (B) selected from organometallic compounds, the metal of which belongs to la, Ila, IIb, Illb or IVb group in the periodic table, and (C) at least one kind of catalyst ingredient (C) selected from halogen-containing compounds comprising halogenated hydrocarbons, halogens, interhalogenous compounds and halides of aluminum, tin, lead, phosphorus, antimony and sulfur. |