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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-732
filingDate 1979-11-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4f355a6585a8a161533d8da30407d078
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7ff3fd8f4ffc46c142a5dfd357f08496
publicationDate 1980-06-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0011855-A1
titleOfInvention Process for the preparation of alkyl esters of unsaturated alpha-hydroxy carboxylic acids
abstract worin R 1 Wasserstoff, Methyl oder Ethyl, R 2 Wasserstoff oder Alkyl mit 1 bis3 C-Atomen und R' Alkyl mit 1 bis 6 C-Atomen bedeutet, wobei man ein Cyanhydrin der allgemeinen Formeln worin R' und R 2 obige Bedeutung haben (oder eine entsprechende Gleichgewichtsmischung aus einem Alkylalkenylketon der Formel CH 2 = CR 1 -CO-CH 2 -R 2 und Blausäure), in Gegenwart von Chlorwasserstoff mit einem Alkohol der allgemeinen Formeln worin R 3 obige Bedeutung hat, umsetzt und das erhaltene Reaktionsgemisch hienach hydrolysiert. Process for the preparation of partially new unsaturated hydroxy esters of the general formula wherein R 1 is hydrogen, methyl or ethyl, R 2 is hydrogen or alkyl having 1 to 3 C atoms and R 'alkyl having 1 to 6 C atoms, wherein a cyanohydrin of the general formula wherein R 'and R 2 have the above meaning (or a corresponding equilibrium mixture of an alkylalkenyl ketone of the formula CH 2 = CR 1 -CO-CH 2 -R 2 and hydrocyanic acid), in the presence of hydrogen chloride with an alcohol of the general formula wherein R 3 has the above meaning, and the reaction mixture obtained is subsequently hydrolyzed. n n n The compounds obtained in this way are suitable for the preparation of alkaloids and crop protection agents and as monomers for copolymerization.
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0110329-A1
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5081276-A
priorityDate 1978-12-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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