http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-104036913-B
Outgoing Links
Predicate | Object |
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classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F19-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01F1-42 |
filingDate | 2014-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2017-01-04-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2017-01-04-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-104036913-B |
titleOfInvention | Magnetic material [Ni2na2(hmb)4(N3)2(CH3cN)2] (CH3cN)2and synthetic method |
abstract | The invention discloses a kind of magnetic material [Ni 2 Na 2 (hmb) 4 (N 3 ) 2 (CH 3 CN) 2 ]·(CH 3 CN) 2 And synthetic method.Magnetic material [Ni 2 Na 2 (hmb) 4 (N 3 ) 2 (CH 3 CN) 2 ]·(CH 3 CN) 2 Molecular formula be: C 40 H 40 Ni 2 N 10 Na 2 O 12 , molecular weight is: 1016.18, Hhmb is 3 methoxyl group 2 hydroxy benzaldehydes.0.114 0.228 grams of analytical pure 3 methoxyl group 2 hydroxy benzaldehydes are dissolved in the mixed solution of 5 10 milliliters of analytical pure absolute methanols and 5 10 milliliters of analytical pure acetonitriles, it is sequentially added into 0.274 0.548g analytical pure six perchloric acid hydrate nickel and 0.098 0.196g analytical pure Hydrazoic acid,sodium salt, add analytical pure triethylamine after stirring to regulate to pH=5.5, stirring, stand, filter, washing, dry.[Ni 2 Na 2 (hmb) 4 (N 3 ) 2 (CH 3 CN) 2 ]·(CH 3 CN) 2 Magnetic property: there is ferromagnetic exchange between intramolecular nickel ion, it shows as ferromagnetism.The present invention has that technique is simple, with low cost, chemical constituent is easily controllable, reproducible and yield advantages of higher. |
priorityDate | 2014-06-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 27.