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Ruszczycky MW, Choi S, Mansoorabadi SO, Liu H. Mechanistic Studies of the Radical S-Adenosyl-l-methionine Enzyme DesII: EPR Characterization of a Radical Intermediate Generated During Its Catalyzed Dehydrogenation of TDP-d-Quinovose. J. Am. Chem. Soc. 2011 Apr 22;133(19):7292–5. doi: 10.1021/ja201212f. |