http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-9735825-A1

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filingDate 1997-03-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_670803b57b92822ec47c0335b663c0c5
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4dcb000b6a3bc907c153b902021ee827
publicationDate 1997-10-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-9735825-A1
titleOfInvention Aldehyde process
abstract A process for the condensation of aldehydes is disclosed in which an aldehyde containing an α hydrogen atom and having the formula R1CHO, wherein R1 is selected from alkyl having one to twelve carbon atoms, and aralkyl having one to fourteen carbon atoms, is combined with hydrated MgO under reaction conditions to form a reaction product mixture comprising an aldol of said aldehyde, the unsaturated aldehyde derived by dehydration of said aldol, or mixtures thereof. In a second embodiment, a first composition selected from aldehydes containing an α hydrogen atom and having the formula R1CHO, wherein R1 is selected from alkyl having one to twelve carbon atoms, and aralkyl having one to fourteen carbon atoms, is combined under reaction conditions with a second different composition selected from aldehydes having the formula R2CHO, wherein R2 is selected from H, alkyl having one to twelve carbon atoms, and aralkyl having one to fourteen carbon atoms, and with hydrated MgO, to form a reaction product mixture comprising an aldol of said aldehyde, the unsaturated aldehyde derived by dehydration of said aldol, or mixtures thereof. Further according to the invention, the aldol or aldehyde formed may be separated from the reaction product mixture, and recovered or treated as desired, or the reaction product mixture may be further directly treated, such as by hydrogenation, to produce a desired product admixture.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6545189-B1
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type http://data.epo.org/linked-data/def/patent/Publication

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