http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-9730095-A1

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filingDate 1996-02-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_16dadcc73b56816105df6d5692ccf1a0
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_71eacbc2183f06255b81814c79ec38f9
publicationDate 1997-08-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-9730095-A1
titleOfInvention Process for producing epoxidized block copolymer
abstract A process for producing an epoxidized block copolymer appropriate for modifying agents or modifying aids for rubbery polymers or resinous polymers, adhesives, sealants, etc. The process comprises epoxidizing a block copolymer which may be partly hydrated and comprises a polymer block (A) containing a vinyl aromatic hydrocarbon compound as the main component and another polymer block (B) containing a conjugated diene compound as the main component to thereby synthesize an epoxidized block copolymer (C) and then recovering this polymer from a slurry or solution thereof in an organic solvent by steam stripping in the presence of a surfactant. It is preferably that the surfactant is a nonionic one, in particular, one represented by the general formula: HO(C2H4O)a(C3H6O)b(C2H4)cOH, wherein a, b and c represent each a number of 1 to 1,000, having an average molecular weight of 3,000 to 20,000 and containing 20 to 90 % by weight of polyoxyethylene. According to the process, the epoxidized block copolymer product can be easily recovered from the reaction mixture without giving any prolonged heat history and thus the epoxy group can be prevented from undergoing ring opening. Also, it is possible to obtain an epoxidized block copolymer having such an epoxy equivalent as to give a high elasticity and the characteristics of epoxy compounds.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111978898-A
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