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filingDate 1994-05-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_74935f44eb086ce2932967f0f07dca3b
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publicationDate 1995-11-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-9531498-A1
titleOfInvention Microporous fast response gels and methods of use
abstract A microporous, cross-linked, reversibly responsive gel obtainable from a polymeric precursor is disclosed. The microporous gels exhibit a volume change response on the order of seconds, many times faster than nonporous volume change gels of similar dimension. A method of making a microporous, fast response and reversibly responsive gel having a defined pore size and defined strut thickness is also disclosed. The method comprises preparing a polymer solution having a certain initial concentration of polymer precursor; initiating phase separation of the polymer to produce a phase separated state; cross-linking the polymer in its phase separated state or cross-linking the polymer prior in its phase separated state, or both prior to and during its phase separated state, for a certain cross-linking reaction time; and allowing gelation to be completed. Particular uses of the fast response gels are also described. In one embodiment, a method for purifying and concentrating a solute from a solution is described. The method includes the steps of contacting a solution containing the solute with the microporous gel of the invention. Next, the gel is swollen to absorb a portion of the solution and exclude the solute by initiating expansion. This results in a concentrated solution of solute and microporous gel swollen primarily with solution lacking solute.
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