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publicationDate 2021-12-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2021247244-A2
titleOfInvention Process for production of thermoplastic vulcanizates using supported catalyst systems and compositions made therefrom
abstract The present disclosure provides a catalyst system comprising the product of a catalyst compound capable of making crystalline material (such as isotactic PP) and a second catalyst compound capable of making non-diene-containing-amorphous material and diene-containing- elastomeric material. The catalyst system of the present disclosure may further comprise a support material (or product thereof) having one or more of: a surface area of from 400 m2/g to 800 m2/g; an average pore diameter of 90 Angstroms or greater; an average particle size of 60 μm or greater; 40% or greater of the incremental pore volume comprising pores having a pore diameter larger than 100 Angstroms or greater; and sub-particles having an average particle size in the range of 0.01 μm to 5 μm. In another embodiment, a propylene polymer composition includes: isotactic polypropylene; 5 wt% or greater of atactic polypropylene, based on the weight of the composition; and an ethylene- propylene-diene terpolymer. The present disclosure further provides methods for forming propylene polymer compositions.
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