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publicationDate 2020-01-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2020012240-A1
titleOfInvention Process and plant for the treatment of a wastewater containing tmah
abstract The present invention describes an innovative process and corresponding plant for the treatment of waste solutions produced by the semiconductor electronics industry. In particular the main object is removal of the TMAH (tetramethyl ammonium hydroxide) molecules and photoresist (mixture of organic solvents) so as to render the solutions more readily treatable in a conventional biological plant, and to avoid disposal of such wastes externally with an obvious increase in management costs. The process provides for three separate treatment lines, each of which processes a specific waste solution: LINE 1 which treats the TMAH solution mixed with that containing the photoresist; LINE 2 which treats another waste containing fluorides, phosphates, ammonia and nitrates; LINE 3 which instead treats a solution characterised by high concentrations of fluorides, nitrates, acetic acid and COD. At the end of the corresponding processes the three solutions are pooled and stored in a common tank, from which a standard activated sludge plant which performs final removal of the ammonia and nitrates is fed. The present invention is therefore included in the group of technologies for the treatment of industrial waste solutions, filling an obvious technological gap in the electronics industry; in fact at the present time the discharge concentration of TMAH, which is approximately 10 mg/L, appears to be too high, while with the present invention values of 0.5 mg/L are obtained, with an obvious improvement in environmental performance and a reduction in external disposal costs.
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