http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2019206324-A1

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filingDate 2019-04-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2019-10-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2019206324-A1
titleOfInvention Combined method for preparing methyl tert-butyl ether and isobutylene from tert-butyl alcohol and methanol
abstract A combined method for preparing methyl tert-butyl ether and isobutylene from tert-butyl alcohol and methanol. The method is carried out in a device comprising a catalytic rectification tower. The catalytic rectification tower comprises a catalytic reaction section located at the middle part, tert-butyl alcohol enters the catalytic rectification tower from the catalytic reaction section, and methanol and water enter the catalytic rectification tower from the tower top. In the catalytic reaction section, a part of tert-butyl alcohol is dehydrated to generate isobutylene, and the other part of tert-butyl alcohol and the isobutylene are respectively further reacted with methanol fed from the tower top to generate methyl tert-butyl ether, wherein the tert-butyl alcohol is pretreated, and the molar feeding ratio of tert-butyl alcohol to methanol is 10:1 to 10:9. The combined process combines reaction and separation, promotes the rightward reaction, enables preparation of isobutylene by means of tert-butyl alcohol dehydration and synthesis of MTBE in "one-pot process", greatly simplifies the operation procedure, lowers the process cost and facilitates implementation, and improves the raw material conversion rate overall.
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