http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2019196041-A1

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filingDate 2018-04-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2019-10-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2019196041-A1
titleOfInvention Chiral main-chain-type azobenzene polymer aggregate and preparation method therefor
abstract The present invention relates to a chiral main-chain-type azobenzene polymer aggregate and a preparation method therefor, which method is specifically operated as follows: respectively taking equal amounts of 1×10-5M of a trichloromethane solution of chiral polysilane and of an azobenzene polymer using a pipette and adding same into a cuvette containing a stirrer; then adding a certain amount of a good solvent, trichloromethane, and stirring same for 2 minutes, and then moving the cuvette to a table; then adding a certain amount of a poor solvent, methanol, along a wall; and gently inverting same 8 times and then leaving same to stand for 2 minutes to obtain the chiral main-chain-type azobenzene polymer aggregate. The present invention provides a new method for preparing the chiral azobenzene polymer aggregate. After a suitable good solvent and poor solvent are found, isomeric aggregates of the main-chain-type azobenzene polymer are successfully prepared by adjusting and controlling the volume ratio of the good solvent and the poor solvent. The chiral polysilane is then selectively and completely decomposed by using ultraviolet light so as to obtain an azobenzene polymer aggregate with a single chirality.
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priorityDate 2018-04-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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