Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_2a819eda0adf22936a52362eeebb9fb4 |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08L2205-025 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G69-32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08L79-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08K3-041 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08K3-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G73-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08L79-00 |
filingDate |
2019-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3ce2e49f89377efc679a105be266a587 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ff632c2c042fa57f4d559efae717769c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_aae14edb200b1166f6d74b3e503e6b8b |
publicationDate |
2019-10-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
WO-2019195442-A1 |
titleOfInvention |
Mechanoresponsive polymers exhibiting low-energy molecular switching |
abstract |
Tunable negative thermal expansion linear polymer materials with reversible large-scale mechanoresponse under low-energy stimulation and fabrication methods are provided. The reversible thermal contraction of the material is due to a molecular switch, s-dibenzocyclooctadiene (DBCOD), which undergoes a twist-boat to chair conformational change when heated or radiated by near-infrared light. The DBCOD moieties are present as either crosslinkers or polymer main-chain units and the corresponding polymers can have different amounts of DBCOD units in the polymer main chain. The various DBCOD monomers can be covalently incorporated into a variety of polymeric materials to construct negative thermal expansion or zero expansion materials for the specific applications. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-11739092-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2021387987-A1 |
priorityDate |
2018-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |