http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2019127305-A1

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publicationDate 2019-07-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2019127305-A1
titleOfInvention Processing method for producing sodium sulfite product by so2 flue gas absorption and arsenic-removal purification using leaching solution of arsenic-containing industrial alkaline residue
abstract Disclosed is a processing method for producing a sodium sulfite product by SO 2 flue gas absorption and arsenic-removal purification using a leaching solution of an arsenic-containing industrial alkaline residue. The method comprises: crushing an arsenic-containing industrial alkaline residue, adding water, pulping, and filter pressing to obtain a leaching solution; adding sodium sulfide aqueous solution and p-phenylenediamine into the leaching solution, followed by filter pressing to obtain a clear arsenic-containing alkaline leaching solution for standby; pumping the clear solution into a spray desulfurization tower to absorb SO 2 , so as to reduce pH value of a resulting absorption solution to about 6.2-6.4, followed by adding the clear arsenic-containing alkaline leaching solution to adjust the pH value to about 10.5~11.5; adding a poly-ferric sulfate aqueous solution for arsenic precipitation and filter pressing so as to perform liquid-solid separation, followed by concentration and evaporation of the clear solution, and then crystallization to separate the mother solution, and finally drying, thereby obtaining a sodium sulfite product having a mass concentration greater than or equal to 96%.
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