http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2019107729-A1

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filingDate 2018-10-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bcb8d09a305b2475d41f548298094ee8
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ffbeb0a41f1f3eadbc889a22e37759cd
publicationDate 2019-06-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2019107729-A1
titleOfInvention Dry cleaning apparatus and method for selectively removing polysilicon
abstract The present invention relates to a dry cleaning apparatus and method for selectively removing polysilicon. The present invention comprises: supplying a fluorine-containing gas in a plasma state and a hydrogen-containing gas in a non-plasma state to a substrate on which a silicon oxide, silicon nitride and polysilicon are formed, so as to change the surface of silicon oxide and silicon nitride into ammonium hexafluorosilicate, thereby forming a protective film; stopping the supply of the hydrogen-containing gas and continuously supplying the fluorine-containing gas in the plasma state so as to selectively remove polysilicon by fluorine radicals; and, finally, a protective film removal step of removing, through annealing, the protective film made of ammonium hexafluorosilicate. According to the present invention, polysilicon can be selectively etched by changing the surface of silicon nitride and silicon oxide, which are formed on a substrate, into an ammonium hexafluorosilicate ((NH 4 ) 2 SiF 6 ) solid layer and using the ammonium hexafluorosilicate solid layer as a protective layer.
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