http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2019011693-A1

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filingDate 2018-07-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b5d3cee6f6c34ddd43cc1e6cf0e7169b
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9d043ffa5c184b7c61077b29abb3bd3d
publicationDate 2019-01-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2019011693-A1
titleOfInvention AQUEOUS BINDER COMPOSITION
abstract The present invention relates to a process for the preparation of an aqueous binder composition, the process comprising at least the following steps A) and B): A) preparation of a carboxylic acid-functional vinyl polymer (polymer A) by polymerization in emulsion of a monomer A composition comprising the following monomers: Ai) at least one carboxylic acid-functional olefinically unsaturated monomer; and Aii) at least one olefinically unsaturated monomer different from Ai); B) preparing the vinyl polymer (polymer B) by emulsion polymerization of a monomer composition B in the presence of the polymer A wherein the monomer composition B comprises the following monomer (s): Bi) at least one olefinically unsaturated monomer; Bii) optionally an olefinically unsaturated monomer having a carboxylic acid functionality other than Bi); wherein at least a portion of the carboxylic acid groups of polymer A is deprotonated to obtain ionic or potentially ionic water dispersion groups; wherein the acid number of the polymer B is lower than the acid number of the polymer A; wherein the weight average molecular weight (Mw) of polymer B is greater than the weight average molecular weight (Mw) of polymer A; wherein the glass transition temperature of polymer B is less than or equal to that of polymer A; wherein the weight ratio of polymer A to polymer B is in the range of 5:95 to 95: 5; and whereby step A) comprises at least a first polymerization stage of a monomer composition (A1) carried out in the presence of a chain transfer agent (C1) having a solubility in water of at least 5 g / l and a second subsequent polymerization stage of a monomer composition (A2) carried out in the presence of a chain transfer agent (C2) having a solubility in water of at most 0.5 g / 1, and whereby the second polymerization stage of step A) is carried out in the optional additional presence of the chain transfer agent (C1) having a solubility in water of at least 5 g / l at wherein the concentration of the chain transfer agent (C1) having a solubility in water of at least 5 g / l in the second polymerization stage of step A) is at most 35 mol% , relative to the total molar concentration of chain transfer agent (C1) and chain transfer agent (C2) present in ns the second polymerization stage of step A).
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2021197883-A1
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priorityDate 2017-07-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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