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filingDate 2017-11-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_048d361270e3521d57b717ff29a61251
publicationDate 2018-05-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2018084189-A1
titleOfInvention Method for producing iridium complex, iridium complex, and light-emitting material comprising said compound
abstract Provided are: a novel method for producing a triscyclometalated iridium complex having three different aromatic heterocyclic ligands which is a complex that has been difficult to be synthesized so far; and a novel iridium complex which is produced by employing the production method, has high solubility in solvents and excellent processability, and can emit light at room temperature with high brightness and with high efficiency. A method for producing a triscyclometalated iridium complex having three aromatic heterocyclic ligands capable of forming an iridium-nitrogen bond and an iridium-carbon bond, wherein the structures of the aromatic heterocyclic ligands are different from one another, said method being characterized by comprising, in the following order, the steps of: (1) reacting a triscyclometalated iridium complex, which has two different aromatic heterocyclic ligands respectively capable of forming an iridium-nitrogen bond and an iridium-carbon bond, with a halogenating agent to introduce a halogen atom into the triscyclometalated iridium complex; (2) converting the halogen atom in the triscyclometalated iridium complex produced in step (1) to a boronic acid ester; and (3) subjecting the triscyclometalated iridium complex produced in step (2) and an organic halogen compound to a cross-coupling reaction to form a carbon-carbon bond.
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