| abstract |
Method for producing silicon particles for use as anode material in lithium ion rechargeable batteries, distinctive by the steps: a)optionally, to introduce silicon seed particles and/or lithium seed particles into, or producing silicon or lithium seed particles or inner core material in a rotatable reactor, as a separate optional step or as included in step b), b)to introduce a silicon-containing first reaction gas for CVD into the reactor, setting the reactor in rotation under CVD-conditions; to grow silicon-rich core particles on the seed particles while the reactor is rotated at a rotational speed creating a centripetal acceleration exceeding at least 1000 times the natural acceleration of gravity on said core particles, c)optionally, to introduce a second reaction gas, liquid or material into the reactor of steps a) and b) or a second reactor into which the core particles of step b) have been introduced; to grow a second material of lower silicon contents than the core material, and the second reaction gas, liquid or material is different from the first reaction gas. The invention also provides silicon particles for use as anode material in lithium ion rechargeable batteries, use of a rotating reactor for the method, and a reactor for operating the method. |