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filingDate 2017-07-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b5d576c20edda2910bad52e412607e03
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publicationDate 2018-01-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2018012385-A1
titleOfInvention Positive electrode active material for nonaqueous electrolyte secondary batteries, transition metal hydroxide precursor, method for producing transition metal hydroxide precursor, method for producing positive electrode active material for nonaqueous electrolyte secondary batteries, electrode for nonaqueous electrolyte secondary batteries, nonaqueous electrolyte secondary battery and electricity storage device
abstract [Problem] To provide: a positive electrode active material which has high discharge capacity per unit volume; a high-density hydroxide precursor for producing this positive electrode active material; an electrode for nonaqueous electrolyte secondary batteries, which uses this positive electrode active material; and a nonaqueous electrolyte secondary battery.n[Solution] A positive electrode active material for nonaqueous electrolyte secondary batteries, which contains a lithium transition metal composite oxide, and wherein: the lithium transition metal composite oxide has an α-NaFeO 2 type crystal structure; the molar ratio of Li to the transition metal (Me), namely, the molar ratio Li/Me is more than 1; the transition metal (Me) comprises Mn and Ni, or Mn, Ni and Co, and the molar ratio Mn/Me is more than 0.5; the lithium transition metal composite oxide has an X-ray diffraction pattern belonging to R3-m; the ratio of the half width of a diffraction peak of the (003) plane to the half width (FWHM(104)) of a diffraction peak of the (104) plane by the Miller indices hkl as obtained by X-ray diffraction measurement using a CuKα ray, namely, (FWHM(003)/FWHM(104)) is 0.6 or less; and the total pore volume as determined by a BJH method from the adsorption isotherm using a nitrogen gas adsorption method is 0.05 cm 3 /g or less.
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