http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2017186566-A1

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publicationDate 2017-11-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2017186566-A1
titleOfInvention Use of a nitrate salt composition as a heat transfer or heat storage medium for first operation of an apparatus containing these media
abstract Use of a nitrate salt composition Z containing Z1 at least one alkali metal nitrate and optionally alkaline earth metal nitrate and Z2 at least one alkali metal nitrite and optionally alkaline earth metal nitrite in an amount of Z2 in the range from 1.1 to 15.0 mol% based on the sum of Z1 plus Z2 as heat transfer or heat storage medium in apparatuses in which these heat transfer or heat storage media are contained at a temperature in the range from 500°C to 620°C and an oxygen partial pressure over the nitrate salt composition in the range from 0.1 to 1.0 atm, characterized in that for a desired temperature selected from the abovementioned range and for a desired oxygen partial pressure selected from the abovementioned range the molar amount of the alkali metal nitrite and optionally alkaline earth metal nitrite is calculated with the following formula (formula I) in which the variables have the following meanings X nitrite is the mole fraction of nitrite in a nitrite/nitrate mixture, K 6 (T) is the temperature-dependent equilibrium constant of the reaction (formula II) oxygen (formula III), pO 2 is the oxygen partial pressure and T is the temperature of the nitrate salt composition and the calculated value of the molar concentration of the component Z2 is optionally reduced by 40% or increased by 20% and wherein the nitrate salt composition Z upon first operation of said apparatuses is heated to a maximum operating temperature in the range from 500°C to 620°C.
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