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filingDate 2017-03-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2017-10-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2017173362-A1
titleOfInvention Selective, adsorbate-induced spin state changes in transition metal-based metal-organic frameworks
abstract An adsorbate-selective metal organic framework includes a transition metal; and a plurality of organic molecules coordinated to the transition metal so as to preserve open coordination sites for selectively adsorbing molecules that have low-lying π* orbitals. The transition metal has a lowest energy spin state in the presence of the selectively adsorbed molecules that are strongly bonding to the transition metal through π-donating interactions which is different than the lowest energy spin state in the absence of these adsorbed molecules. The transition metal has also a lowest energy spin state in the presence of non-selected molecules that are weakly bonding to the transition metal through σ- and/or π-accepting and/or donating interactions.
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