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filingDate 2017-02-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f56ba548a692ad0efe5b1b0bd243b8b2
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publicationDate 2017-08-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2017137154-A1
titleOfInvention Method for grafting polysiloxanes on surfaces of photocatalytic metal oxides, polysiloxane-grafted metal oxide surfaces and applications thereof
abstract The present invention relates to a method for grafting polysiloxanes on surfaces of photocatalytic metal oxides by light illumination which comprises at least the following steps : a) providing a surface of a photocatalytically active metal oxide; b) providing a polysiloxane or a mixture of polysiloxanes on the metal oxide surface; c) irradiating the reaction mixture with light in a wavelength range from 180 nm to 550 nm for a sufficient time to generate reactive moieties in said polysiloxanes and to form covalent Si-O-Me (Me = metal) bonds between said reactive moieties of the polysiloxanes and the metal oxide surface; d) optionally separating unreacted polysiloxane molecules from the polysiloxane-grafted metal oxide surface; wherein no silane coupling agent or cross-linking agent is present in the reaction mixture and/or participates in said grafting reaction. A further aspect of the invention relates to the hydrophobic and photocatalytically active polysiloxane-grafted metal oxide surface obtainable by said method and to articles comprising said surface.
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