http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2017076947-A1

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filingDate 2016-11-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_02d948ce3e7271dce4c5ced8c662d583
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_59473069d29399ba430faa092cd876d1
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publicationDate 2017-05-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2017076947-A1
titleOfInvention Process for preparing furan-2,5-dicarboxylic acid
abstract The invention relates to a process for preparing furan-2,5-dicarboxylic acid comprising the following steps: (a) preparing or providing a starting material mixture comprising 5-(hydroxymethyl)furfural (HMF) as a first reactant and one or more second reactants selected from the group consisting of esters of 5-(hydroxymethyl)furfural and ethers of 5-(hydroxymethyl)furfural, (b) subjecting said starting material mixture to first oxidation conditions at a temperature in the range TR1 of from 110 to 140 °C so that an amount of said 5-(hydroxymethyl)furfural (HMF) present in the starting material mixture is oxidised to furan-2,5-dicarboxylic acid and a first product mixture results comprising furan-2,5-dicarboxylic acid and an unreacted amount of said one or more second reactants, and (c) subjecting the first product mixture obtained in step (b) or a mixture obtained from the first product mixture obtained in step (b) by additional treatment steps to second oxidation conditions at an increased temperature in the range TR2 of from above 140 to 200 °C so that said at least a fraction of said unreacted amount of said one or more second reactants present in the first product mixture is oxidised and a second product mixture results comprising furan-2,5-dicarboxylic acid.
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