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filingDate 2016-05-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ee2a89f7b0b141a1b26a09d7dd9322cb
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publicationDate 2016-12-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2016193171-A1
titleOfInvention Transparent, essentially colorless, tin-fined las glass-ceramics with improved microstructure and thermal expansion properties
abstract The object of the present application is β-quartz glass-ceramics (having very interesting optical, thermal expansion and feasibility properties), the articles including said glass-ceramics; the precursor glasses of said glass-ceramics, as well as the methods for elaborating said glass-ceramics and said articles. Said glass-ceramics having a composition, free, except for inevitable trace amounts, of arsenic oxide, antimony oxide and rare earth oxide, which contains, expressed in percentages by weight of oxides: 64 to 70% of SiO 2 , 18 to 24% of Al 2 O 3 , 4 to 5% of Li 2 O, 0 to 0.6% of SnO 2 , >1.9 to 4% of TiO 2 , 1 to 2.5% of ZrO 2 , 0 to 1.5% of MgO, 0 to 3% of ZnO, >0.3 to 1 of CaO, 0 to 3% of BaO, 0 to 3% of SrO, with BaO + SrO ≤ 3 %, 0 to 1.5% of Na 2 O, 0 to 2% of K 2 O, with 0.2 <(MgO + Na 2 O + K 2 O)/Li 2 O ≤ 1, 0 to 3% of P 2 O 5 , less than 250 ppm of Fe 2 O 3 ; and their crystallites, present in said β-quartz solid solution, have an average size of less than 40 nm, advantageously less than 35 nm, very advantageously less than 30 nm.
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priorityDate 2015-05-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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