Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_2efbe95965e682e179dfd266c9980505 |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-49 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0227 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-0225 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D307-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D307-12 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D493-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D307-02 |
filingDate |
2014-11-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_64bcd6279bc024f6fb8feec6217bd642 |
publicationDate |
2016-05-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
WO-2016081010-A1 |
titleOfInvention |
Acid-catalyzed acylation of 5-(hydroxylmethyl)-furfural reduction products |
abstract |
An improved process for acid-catalyzed acylation using water-tolerant Lewis acid catalysts is described. The method involves reacting a reduction products of 5-(hydroxylmethyl)-furfural (HMF), in particular either furan-2,5-dimethanol (FDM) or bis -2,5-(hydroxymethyl)-tetrahydrofuran (bHMTHFs), with an excess of an organic acid in the presence of a Lewis acid metal triflate at a temperature and time sufficient to produce esters. The conversions of the reduction products of HMF to corresponding diesters can be quantitative with certain favored Lewis acids catalysts. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-107686470-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2019224027-A1 |
priorityDate |
2014-11-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |