http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2015139029-A3

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filingDate 2015-03-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d5d3f16ca97658c4910bb475b3a60cec
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publicationDate 2015-11-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2015139029-A3
titleOfInvention Polysaccharide derivatives and cross-metathesis processes for preparing them
abstract Methods for the cross-metathesis of polysaccharides with one or more olefin-terminated side chains and cross-metathesized products are described. In an exemplary embodiment, a method for the synthesis of cellulose ω-carboxyesters via olefin cross-metathesis with acrylates is described. Conditions of the reactions were relatively mild and the olefin-substituted polysaccharides and the appropriate acrylate partners appear to follow Grubbs rules as summarized herein. Additionally, a method of hydrogenation of the cross-metathesized product is described. The compounds and methods may be useful for waterborne coating applications, adhesives, lubricants, or any product in need of dispersion in an aqueous media.
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